Please use this identifier to cite or link to this item: http://earchive.tpu.ru/handle/11683/35480
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dc.contributor.authorGalanov, S. I.en
dc.contributor.authorSidorova, O. I.en
dc.contributor.authorGavrilenko, Mikhail Alekseevichen
dc.date.accessioned2016-12-16T03:20:30Z-
dc.date.available2016-12-16T03:20:30Z-
dc.date.issued2014-
dc.identifier.citationGalanov, S. I.. The Process of Acetonitrile Synthesis over γ-Al[2]O[3] Promoted by Phosphoric Acid Catalysts [Electronic resource] / S. I. Galanov, O. I. Sidorova, M. A. Gavrilenko // Procedia Chemistry . — 2014 . — Vol. 10 : Chemistry and Chemical Engineering in XXI century . — [P. 108-113] .en
dc.identifier.urihttp://earchive.tpu.ru/handle/11683/35480-
dc.description.abstractThe influence of principal parameters (reaction temperature, ratio of acetic acid and ammonia, composition of reactionary mixture and promotion of catalysts) on the selectivity and yield of the desired product was studied in the reaction of catalytic acetonitrile synthesis by ammonolysis of acetic acid. The processing of [gamma]-Al[2]O[3] by phosphoric acid increases amount of the centers, on which carries out reaction of acetamide dehydration. The kinetic model of a limiting stage of reaction - the acetamide dehydration to acetonitrile was suggested. In the process of ammonolysis of acetic acid it was demonstrated that the use of catalysts promoted by phosphoric acid and ratio NH[3]:CH[3]COOH=(3-4):1 at temperatures of a reactor 360-390°С leads to the increase of acetonitrile productivity to 0.7-0.8 g/cm{3}·h and allows to minimize formation of by-products.en
dc.language.isoenen
dc.publisherElsevierru
dc.relation.ispartofProcedia Chemistry. Vol. 10 : Chemistry and Chemical Engineering in XXI century, 2014.en
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.subjectкатализаторыru
dc.subjectсинтезru
dc.subjectацетонитрилru
dc.subjectоксид алюминияru
dc.subjectуксусная кислотаru
dc.subjectацетамидru
dc.subjectфосфорная кислотаru
dc.subjectкатализаторыru
dc.subjectcatalystru
dc.subjectsynthesis of acetonitrileru
dc.subjectaluminaru
dc.subjectacetic acidru
dc.subjectacetamideru
dc.titleThe Process of Acetonitrile Synthesis over γ-Al[2]O[3] Promoted by Phosphoric Acid Catalystsen
dc.typeConference Paperen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.typeinfo:eu-repo/semantics/conferencePaperen
dcterms.audienceResearchesen
local.departmentНациональный исследовательский Томский политехнический университет (ТПУ)::Институт природных ресурсов (ИПР)::Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)ru
local.description.firstpage108-
local.description.lastpage113-
local.filepathhttp://dx.doi.org/10.1016/j.proche.2014.10.020-
local.identifier.bibrecRU\TPU\network\3951-
local.identifier.colkeyRU\TPU\col\18659-
local.identifier.perskeyRU\TPU\pers\33857-
local.localtypeДокладru
local.volume10-
local.conference.nameChemistry and Chemical Engineering in XXI century-
local.conference.date2014-
dc.identifier.doi10.1016/j.proche.2014.10.020-
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