Самособирающиеся магнитные материалы, формирующиеся посредством невалентных взаимодействий

Abstract

Magnetic materials are used in such scientific fields as computation, and electronics, especially as a memory unit of electronic devices. Common magnetic materials have inorganic base like metals or their oxides but their main disadvantage is the difficulties in spin-spin interactions control in such structures. This problem could be solved by using of organic-based magnetic materials which dramatically expand the field of their application. Organic-based materials could be used in new scientific areas like molecular spintronics, quantum technologies, metal-organic frameworks (MOFs), and 2D materials. At the same time, weak magnetic properties of organic-based materials are still challenging task and its solvation was proposed by stable radical-based multispin systems. Nevertheless, their synthesis is limited by hard to handle procedures. We propose to avoid this issue by using of non-covalent interactions instead of commonly used covalent bonding. In the present study, we investigated the possibility of the formation of non-covalent interaction between π-conjugated system and nitronyl-nitroxide radical. Obtained results will be play a pivotal role in the design of new self-assembled organic-based magnetic materials.