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http://earchive.tpu.ru/handle/11683/14875
Полная запись метаданных
Поле DC | Значение | Язык |
---|---|---|
dc.contributor.author | Usoltseva, Natalia Vasilievna | ru |
dc.contributor.author | Korobochkin, Valery Vasilievich | ru |
dc.contributor.author | Balmashnov, Mikhail Aleksandrovich | ru |
dc.contributor.author | Dolinina, Alesya Sergeevna | ru |
dc.date.accessioned | 2016-03-18T07:58:54Z | - |
dc.date.available | 2016-03-18T07:58:54Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Solution Transformation of the Products of AC Electrochemical Metal Oxidation / N. V. Usoltseva [et al.] // Procedia Chemistry. — 2015. — Vol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015) : XVI International Scientific Conference dedicated to Professor L.P. Kulyov, 25-29 May 2015, Tomsk, Russia. — [P. 84-89]. | ru |
dc.identifier.uri | http://earchive.tpu.ru/handle/11683/14875 | - |
dc.description.abstract | Electrochemical oxidation of copper and aluminium using alternating current of industrial frequency results in the formation of non-equilibrium products. Their transformations during the ageing in sodium chloride solutions of different concentrations have been considered. According to X-Ray diffraction confirmed by TG/DSC/DTG analysis, irrespective of solution concentration, the ageing products consist of aluminium oxyhydroxide (boehmite, AlOOH), copper-aluminium carbonate hydroxide hydrate (Cu-Al/LDH) and copper chloride hydroxide (Cu[2](OH)[3]Cl). The increase of the solution concentration leads to Cu[2](OH)[3]Cl formation and makes difficulties for metal oxide carbonization to Cu-Al/LDH. Ageing in highly diluted solution contributes not only to Cu-Al/LDH formation but also boehmite hydration that is verified by IR-spectra. The pore structure characteristics have been also discussed. They do not significantly depend on phase composition and vary in ranges of 161.2-172.6 m{2}/g (specific surface areas), 0.459-0.535 cm{2}/g (total pore volumes). Pore size distributions reveal that a pore structure is predominantly formed by pore with the sizes from 3 to 22°nm; 3.6°nm is the size of pores with the largest pore volume. | ru |
dc.language.iso | en | en |
dc.publisher | Elsevier | ru |
dc.relation.ispartof | Procedia Chemistry. Vol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015). — Amsterdam, 2015. | ru |
dc.rights | info:eu-repo/semantics/openAccess | en |
dc.subject | электролиз | ru |
dc.subject | оксид меди | ru |
dc.subject | оксид алюминия | ru |
dc.subject | хлорид натрия | ru |
dc.subject | дифракция | ru |
dc.subject | рентгеновские излучения | ru |
dc.subject | ИК-спектры | ru |
dc.title | Solution Transformation of the Products of AC Electrochemical Metal Oxidation | ru |
dc.type | Conference Paper | en |
dc.type | info:eu-repo/semantics/publishedVersion | en |
dc.type | info:eu-repo/semantics/conferencePaper | en |
dcterms.audience | Researches | en |
local.department | Национальный исследовательский Томский политехнический университет (ТПУ)::Институт физики высоких технологий (ИФВТ)::Кафедра общей химии и химической технологии (ОХХТ) | ru |
local.department | Национальный исследовательский Томский политехнический университет (ТПУ)::Институт природных ресурсов (ИПР)::Кафедра иностранных языков (ИЯПР) | ru |
local.description.firstpage | 84 | - |
local.description.lastpage | 89 | - |
local.filepath | http://dx.doi.org/10.1016/j.proche.2015.10.013 | - |
local.identifier.bibrec | RU\TPU\network\10398 | - |
local.identifier.colkey | RU\TPU\col\21253 | - |
local.identifier.colkey | RU\TPU\col\18662 | - |
local.identifier.perskey | RU\TPU\pers\31509 | - |
local.identifier.perskey | RU\TPU\pers\31050 | - |
local.identifier.perskey | RU\TPU\pers\33896 | - |
local.identifier.perskey | RU\TPU\pers\33893 | - |
local.localtype | Доклад | ru |
local.volume | 152015 | - |
local.conference.name | Chemistry and Chemical Engineering in XXI century | - |
local.conference.date | 2015 | - |
dc.identifier.doi | 10.1016/j.proche.2015.10.013 | - |
Располагается в коллекциях: | Материалы конференций |
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Файл | Описание | Размер | Формат | |
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j.proche.2015.10.013.pdf | 666 kB | Adobe PDF | Просмотреть/Открыть |
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