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Title: | Oxidation and Structuring of Polydicyclopentadiene Thin Layers |
Authors: | Lyapkov, Aleksey Alekseevich Gvozdkov, E. L. Tarakanovskaya, A. N. Tarnovskaya, O. D. Yakovleva, Y. S. |
Keywords: | окисление; структурирование; полидициклопентадиен; катализаторы; полимеризация; тонкие слои; тетрахлорид титана; окисление; сшивание; catalytic polymerization; polydicyclopentadiene thin layers; titanium tetrachloride; triisobuthylaluminum; original Hoveyda–Grubbs II type catalyst; oxidation; cross-linking |
Issue Date: | 2014 |
Publisher: | Elsevier |
Citation: | Oxidation and Structuring of Polydicyclopentadiene Thin Layers [Electronic resource] / A. A. Lyapkov [et al.] // Procedia Chemistry . — 2014 . — Vol. 10 : Chemistry and Chemical Engineering in XXI century . — [P. 223-228] . |
Abstract: | It has been shown that polymeric film coatings derived from polydicyclopentadiene are subject to oxidation and structuring in air. Oxidation in air of double bonds in films gradually happens during several weeks and it comes amid an increase of adsorption band of carbonyl and hydroxyl groups in polymers infrared spectrums. Moreover, because of selective oxidation of cis-configured chains, structuring occurs around the double bonds in the polymer chain in polydicyclopentadiene films acquired by metathesis polymerization. |
URI: | http://earchive.tpu.ru/handle/11683/35499 |
Appears in Collections: | Материалы конференций |
Files in This Item:
File | Description | Size | Format | |
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dx.doi.org-10.1016-j.proche.2014.10.038.pdf | 487,35 kB | Adobe PDF | View/Open |
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