Investigation of influence of electromagnetic field on electrochemical behaviour of heavy metal ions in the presence of butanol

Abstract

By the method of inversion voltamperometry the action of high-frequency electromagnetic field of radio-frequiency bandwidth on current of anode peak Zn(II), Cd(II) and Pb(II) in the presence of butanol, molecules of which are adsorbed on the electron surface decreasing its free surface has been studied. As a result of the field influence on electrode-electrolyte system removing of electrode processes inhibition is shown to take place, it is conditioned by desorbtion of adsorbate molecules from electron surface. Desorbing action of high-frequency current is proved by measuring degree of electrode filling with butanol molecules and Frumkin's adsorbtion equation parameters.