Новая модель эффективного дипольного момента молекул типа аксиальной симметрии C3v: приложения к исследованию абсолютных интенсивностей в полосе ν6 молекулы CH₃³⁵Cl

Abstract

The effective dipole moment model for molecules of axial C3v symmetry is derived on the basis of the symmetry properties of a molecule which, on the one hand, is of the same order of efficiency (but much simpler and clearer in applications) as the analogous models derived on the basis of the irreducible tensorial sets theory, and, on the other hand, mathematically more correct in comparison with concepts like the Herman-Walles function used in the models. For the ν6 fundamental of CH3 35Cl the computer code was used for determination of the parameters of the derived effective dipole moment model