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Название: Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol
Авторы: Sechin, Aleksandr Ivanovich
Kyrmakova, O. S.
Ivanova, T. A.
Ключевые слова: термодинамические расчеты; разложение; пары; этиловый спирт
Дата публикации: 2015
Издатель: IOP Publishing
Библиографическое описание: Sechin A. I. Carrying out thermodynamic calculations and definition of the main reactions of decomposition of vapours of ethyl alcohol / A. I. Sechin, O. S. Kyrmakova, T. A. Ivanova // IOP Conference Series: Materials Science and Engineering. — 2015. — Vol. 81 : Radiation-Thermal Effects and Processes in Inorganic Materials : International Scientific Conference, 3-8 November 2014, Tomsk, Russia : [proceedings]. — [012109, 5 p.].
Аннотация: Thermodynamic opportunities of course of chemical reactions of decomposition of the vapors of ethyl alcohol necessary at development of devices where these reactions will take place are considered. The entalpiyny method of calculation of constants of balance of probable chemical reactions is given in the Excel editor. Independent reactions of process of oxidation are defined. By result of thermodynamic calculation of each reaction schedules of dependence of a constant of balance on environment temperature from which follows are constructed that one reactions proceed until the end of aside formation of the final products, and others are improbable or impossible. The analysis of the received results shows that reactions of oxidation will successfully proceed in the established directions, and for an intensification of process of decomposition it is necessary to provide a supply of some energy which quantity will be sufficient for oxidation of vapors of ethyl alcohol. Results of calculations showed good convergence with programs of thermodynamic calculations like "Aster-4" and "TERRA".
URI: http://earchive.tpu.ru/handle/11683/14753
Располагается в коллекциях:Материалы конференций

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