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http://earchive.tpu.ru/handle/11683/15061| Title: | Research of the Formation of Regularities Siloxane Norbornene Derivatives by Thermal Diels-Alder Reaction |
| Authors: | Bondaletov, Vladimir Grigoryevich Troyan, Anna Alekseevna Kuhlenkova, N. O. Netesova, Mariya Vitalevna Zamanova, Margarita Karimovna |
| Keywords: | циклопентадиен; димеризация; дициклопентадиен; реакция Дильса-Альдера; винилтриэтоксисилан; силаны; норборнен |
| Issue Date: | 2015 |
| Publisher: | Elsevier |
| Citation: | Research of the Formation of Regularities Siloxane Norbornene Derivatives by Thermal Diels-Alder Reaction / V. G. Bondaletov [et al.] // Procedia Chemistry. — 2015. — Vol. 15 : Chemistry and Chemical Engineering in XXI century (CCE 2015) : XVI International Scientific Conference dedicated to Professor L.P. Kulyov, 25-29 May 2015, Tomsk, Russia. — [P. 259-264]. |
| Abstract: | The methods of chromatography-mass spectrometry and 1H NMR-spectroscopy were used to study the reaction between dicyclopentadiene and vinyltriethoxysilane. The main reaction products are exo- and endo-isomers bicycle [2.2.1] hept-5-en-2-yl(triethoxy)silane. The overall yield of isomers is 55% of the load components. Co-products are the alkoxysilyl derivatives of dicyclopentadiene. Also the authors of the article paid attention to the problems of the time and temperature reaction, and ratios of starting components on chemical yield. |
| URI: | http://earchive.tpu.ru/handle/11683/15061 |
| Appears in Collections: | Материалы конференций |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| j.proche.2015.10.041.pdf | 452,57 kB | Adobe PDF | View/Open |
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