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http://earchive.tpu.ru/handle/11683/35498| Title: | Dicyclopentadiene Polymerization in Solutions under the Action of Various Catalytic Systems |
| Authors: | Lyapkov, Aleksey Alekseevich Gvozdkov, E. L. Tarakanovskaya, A. N. Tarnovskaya, O. D. Yakovleva, Y. S. |
| Keywords: | полимеризация; дициклопентадиен; растворы; каталитические системы; катализаторы; тетрахлорид титана; адиабатические реакторы; термомеханические методы; константы; толуолы; catalytic polymerization; dicyclopentadiene; titanium tetrachloride; triisobuthylaluminum; original Hoveyda–Grubbs II type catalyst; adiabatic reactor; thermometric method; rates constants |
| Issue Date: | 2014 |
| Publisher: | Elsevier |
| Citation: | Dicyclopentadiene Polymerization in Solutions under the Action of Various Catalytic Systems [Electronic resource] / A. A. Lyapkov [et al.] // Procedia Chemistry . — 2014 . — Vol. 10 : Chemistry and Chemical Engineering in XXI century . — [P. 217-222] . |
| Abstract: | The kinetics of dicyclopentadiene polymerization in toluene solution under the action of different catalytic systems through adiabatic thermometry was investigated. Unlike cationic metathesis polymerization has a sufficiently large induction period associated with low speed by implantation monomer on carbine bond of catalyst. It has been shown that the rate of metathesis polymerization of dicyclopentadiene in comparable circumstances is about three times lower than the rate of cationic polymerization of the same monomer. |
| URI: | http://earchive.tpu.ru/handle/11683/35498 |
| Appears in Collections: | Материалы конференций |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| dx.doi.org-10.1016-j.proche.2014.10.037.pdf | 631,48 kB | Adobe PDF | View/Open |
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