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http://earchive.tpu.ru/handle/11683/132867| Title: | Первые исследования сверхтонкой квадрупольной вращательной структуры винилхлорида (C2H3 35Cl) в высоковозбужденных вращательных состояниях |
| Other Titles: | The study of the hyperfine quadrupole rotational structure of vinyl chloride (C2H3 35Cl) in highly excited rotational states up to 1.1 THz |
| Authors: | Худякова, Ю. В. |
| metadata.dc.contributor.advisor: | Громова, Ольга Васильевна |
| Keywords: | vinyl chloride; submillimeter-wave spectroscopy; hyperfine structure; rotational spectroscopy |
| Issue Date: | 2025 |
| Publisher: | Томский политехнический университет |
| Citation: | Худякова, Ю. В. Первые исследования сверхтонкой квадрупольной вращательной структуры винилхлорида (C2H3 35Cl) в высоковозбужденных вращательных состояниях / Ю. В. Худякова ; науч. рук. О. В. Громова // Перспективы развития фундаментальных наук. — Томск : Изд-во ТПУ, 2025. — Т. 1 : Физика. — С. 269-271. |
| Abstract: | In the present study, the analysis of high-resolution rotational spectra of C2H3 35Cl was performed. The absorption spectra were registered in submillimeter-wave regions from 170 up to 1100 GHz in Universität zu Köln (Germany). About 5100 line positions for the values of quantum numbers up to Jmax = 93 and Kmax a = 27 were assigned to the ground vibrational state. The fit of the parameters of the Hamiltonian and of the quadrupole splitting χ−parameters was made. The obtained set of twenty three rotational and centrifugal distortion parameters and two χ−parameters reproduces quadrupole-rotational transitions with the drms = 20 kHz |
| URI: | http://earchive.tpu.ru/handle/11683/132867 |
| Appears in Collections: | Материалы конференций |
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| File | Size | Format | |
|---|---|---|---|
| conference_tpu-2025-C21_V1_p269-271.pdf | 796,19 kB | Adobe PDF | View/Open |
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