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http://earchive.tpu.ru/handle/11683/5767| Title: | Interaction of substituted aril iodide with protonic acid |
| Authors: | Chaykovskiy, V. К. Funk, А. А. Kozlova, N. S. Kets, Т. S. |
| Keywords: | substituted aril iodide; protonic acid; calculations; free energy; Gibbs energy; enthalpy; direct reactions; reverse reactions; mineral acids; experimental tests; theoretical results; electron density; iodoaniline |
| Issue Date: | 2007 |
| Publisher: | Томский политехнический университет |
| Citation: | Interaction of substituted aril iodide with protonic acid / V. К. Chaykovskiy [et al.] // Bulletin of the Tomsk Polytechnic University. — 2007. — Vol. 310, № 1. — [P. 149-151]. |
| Abstract: | Using GAUSSIAN'98W program package calculation of Gibbs free energy, activation enthalpy and free activation energy of direct and reverse interaction reaction of substituted aryl iodides with mineral acids has been carried out. Experimental test of the obtained theoretical results is performed. HI is shown to demonstrate a strong deiodinating affect only on the compounds with high ?-electron density. HCl, H3PO4 and H2SO4 deiodinate partially only 4-iodoaniline. |
| URI: | http://earchive.tpu.ru/handle/11683/5767 |
| Appears in Collections: | Известия Томского политехнического университета. Инжиниринг георесурсов |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| bulletin_tpu-2007-310eng-1-38.pdf | 297,1 kB | Adobe PDF | View/Open |
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